The Shopify platform does the actual sending of invitation emails, whereas the WOTIO app simply initiates the sending request, therefore you must look at your email set up within the Shopify platform. Shopify has addressed the cause of bouncebacks by providing this article on how to resolve the issue of bouncebacks for your store:

https://community.shopify.com/c/Shopify-Discussion/Resolving-Bounce-Backs-and-Via-Shopify-com/td-p/653804